I think the Synthetic ATF will be one of the best things you can do. Mobil 1 or Amsoil come to one mind. $120 of Mobil 1 will go a long way to helping your transmission. Increased capacity of the ATF cannot hurt. The 4 quart pans add about 25% more volume to the system. Have yet to see any real data on aluminum pans vs steel pans in relation to ATF temperatures.
83 C10 Suburban, Silverado, 6.2, 700R4, 3.73, 31-10.50R15
82 C30 Crew Cab dually, 6.2, Banks, Th400, 4.10, Gear Vendors, 235-85R16
83 C20 Suburban, Sierra Classic, 6.2, 700R4, 4.10, custom paint, 285-50R20
95 Yukon, 6.5, 4L80E, 3.42, 265-50R20
73 GMC Astro 95, 8V71, 10 speed Roadranger, 110" WB, 6 each 11R24.5